Материал: Документ
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№ 4 (19), 2018 |
. 3. α і (1)
: 2 – 20 1; 3 – 20 2; 4 – 20 4; 5 – 20 5
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: Co + 4Cl– = [CoCl4]2- + 2ē. |
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(2H2O – 4ē = O2 + 4H+), |
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τ τa. |
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τ τa, = 20 1 |
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τ τa |
20 5 – |
– 0,1 %. |
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120
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№ 4 (19), 2018 |
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Д1ηЖ. |
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α – Co |
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pH |
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Д16Ж. |
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0,83·105 |
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з 1,7 |
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. ζ. |
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121
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1. |
. ., |
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. 1957. 647 . |
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2. |
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/ . . |
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, 1975. 552 . |
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Moral F.R. Electroplating of cobalt and cobalt alloys a review // Plating. |
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1967. Vol. η, № 6. P. 693-701. |
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ζ. |
. . |
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. 2004. .12. № 1. |
.16-18. |
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5.Barrett R.C. Plating of nicel, cobalt, iron and cadmium from sufamat soulution //Tech Proc. Amer. Eltctrohlaters Soc., 1960. V.47. P. 170-175.
6.Venkatachalam S., Rama Char T.L. Electrodeposition of cobalt from the
sulfamat bath // Plating, 1963, V.61. № 3. P. 6267.
7. |
. . |
. .: |
- |
,1977. 9ζ .
8.Belt K.C., Grossley L.A., Watson S.A. Nicel-cobalt alloy deposits from concentrated sulfamate electrolyte // Trans. Ins. Metal Finich, 1970/ v. 48. № ζ. P. 133-138.
9.Bennighoff Hanns. Wirtshahaftliches Galvanoformen mit Nicel-cobalt //
Metall (W-Berlin), 1979. B. 33. № 3. P. 295-296.
10. |
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. . |
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, 2003. .76. |
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. 1. . 67-72. |
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11. |
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, 1978. 267 . |
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122
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№ 4 (19), 2018 |
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12. |
. . № 37ζ382 |
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232 b 15/00. 1973. |
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. 32-37. |
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№ 2340709 |
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23 b η/08. |
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. 22.03.2007; №2007710620/02; |
. 10.12.2008. |
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. 2018. |
. № 2(17). |
. 100-108. |
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17. |
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, 1972. 320 . |
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18. |
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19. |
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20. |
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. // C. . |
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. ., |
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. 2017. № ζ(20). |
. 86˗93. |
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21. |
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. ., |
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. 1989. 136 . |
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№ 4 (19), 2018 |
REFERENCE
1.Liner V.I., Kudryavtsev N.T. Essentials of electroplating. M.: Publishing house of ferrous and nonferrous metallurgy. 1957. 647 p.
2.Applied electrochemistry / N.T. Kudryavtsev. M.: Chemistry, 1975.
552 p.
3.Moral F.R. Electroplating of cobalt and cobalt alloys a review // Plating. 1967. Vol. 5, No. 6. P. 693-701.
4.Elinek T.V. Successes of electroplating // Electroplating and surface
ЭЫОКЭЦОЧЭ. 200ζ. V. 12. № 1. . 16-18.
5.Barrett R.C. Plating of nice, cobalt, iron and cadmium from sufamat soulution // Tech Proc. Amer. Eltctrohlaters Soc., 1960. V.47. P. 170-175.
6.Venkatachalam S., Rama Char T.L. Electrodeposition of cobalt from the sulfamat bath // PХКЭТЧР, 1963, V.61. № 3. P. 62-67.
7.Vyacheslav P.M. Electrolytic deposition of alloys. L.: Mechanical Engineering, 1977. 94 p.
8.Belt K.C., Grossley L.A., Watson S.A. Nice-cobalt alloy deposits of concentrated sulfamate electrolyte // Trans. Ins. Metal Finich, 1970 / v. 48. No. 4. P. 133-138.
9.Bennighoff Hanns. Wirtshahaftliches Galvanoformen mit Nicel-cobalt // Metall (W-Berlin), 1979. B. 33. No. 3. P. 295-296.
10.Spiridonov B.A. The study of the process of electrodeposition of chro- mium-cobalt alloy coatings from sulphate solutions. Journal of Applied Chemistry, 2003. T.76. Issue 1. P. 67-72.
11.Purin B.A., Tsera V.A., Ozola E.A., Vitinya I.A. Complex electrolytes in electroplating. Riga: Liesma, 1978. 267 p.
12.A.S. No. 374382 USSR, MKI S 232 b 15/00. 1973. Method of electro-
lytic cobalt / Kiselev O.B., Purin B.A., Ozol-Kalnin. (THE USSR). No. 2781033;
НОМХКЫО 20.10. 73; ЩЮЛХ. 03/30/7ζ. BЮХХ № 1η. 2 p.
13. Spiridonov B.A., Zavalishin M.A. The study of the electrodeposition of
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